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Conformality → ALD >> PECVD >> Sputter >>> Evaporation
Transport of reactants to the substrate
- Case 1: direct $\left( S_c=1\right)$
- Case 2: re-emission $\left( S_c<1\right)$
- Case 3: Surface diffusion
Reactive sticking coefficient $S_c$
$$ S_c=\cfrac{incident-re\;emitted}{incident\;precursor} $$
If $S_c \approx1$, non-conformal
$S_c <1,$ conformal
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