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s, p, d bands

by 도른자(spinor) 2023. 6. 26.
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sp-band

 

d-orbital = transport 할 때는 중요핮 ㅣ않다.

well-localized: important magnetic property. (magnetic property 결정할때는 중요!) In transition metals, d orbit is not important in the chemical properties

 

small band width, large D(E)

spin-dependent scattering => d-orbital 자리 많아서?

In transition metals, d orbit is not important in the cemical properties

DOI: 10.13140/RG.2.1.1837.4086/1

sp = 날씬: parabolic (Density of states가 적어서 질량 적고, free)

d = 뚱뚱: DOS 커서 질량 커지고, localized

 

Hybridization of Bands

s-electrons are more spread out, so that it has large $\beta$ than d-electron.

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